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11 September, 19:41

Describe how you could use IR spectroscopy to distinguish between ethyl acetate and butyric acid. The IR spectrum of butyric acid should have a broad signal between 1650 cm-1 and 1850 cm-1. An IR spectrum of ethyl acetate will not have this signal. The IR spectrum of butyric acid should have a broad signal between 2500 cm-1 and 3600 cm-1. An IR spectrum of ethyl acetate will not have this signal. The IR spectrum of ethyl acetate should have a broad signal between 2500 cm-1 and 3600 cm-1. An IR spectrum of butyric acid will not have this signal. The IR spectrum of ethyl acetate should have a broad signal between 1650 cm-1 and 1850 cm-1. An IR spectrum of butyric acid will not have this signal.

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  1. 11 September, 19:48
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    The IR spectrum of butyric acid should have a broad signal between 2500 cm⁻¹ and 3600 cm⁻¹. An IR spectrum of ethyl acetate will not have this signal.

    Explanation:

    IR spectroscopy is a widely used technique in chemical identifications. In a IR spectrum, signals depend of nature of bonds in the chemical structure of the compound.

    Ethyl acetate is an esther. Its principal signal is between 16500cm⁻¹ and 1850cm⁻¹ (Carboxylic compound).

    Butyric acid is a carboxylic acid. Carboxylic acids have 2 principal signals: The first is between 16500cm⁻¹ and 1850cm⁻¹ (Carboxylic compound) and the second is between 2500cm⁻¹ and 3600cm⁻¹ (Due the hydrogen bonding between O-H atoms).

    Thus, right answer is:

    The IR spectrum of butyric acid should have a broad signal between 2500 cm⁻¹ and 3600 cm⁻¹. An IR spectrum of ethyl acetate will not have this signal.
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