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25 November, 15:04

Which of the following combinations will result in a reaction that is never spontaneous?

positive enthalpy change and positive entropy change

positive enthalpy change and negative entropy change

negative enthalpy change and positive entropy change

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  1. 25 November, 15:23
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    Positive change in enthalpy and negative change in entropy.

    Explanation:

    Remember that any spontaneous process must lead to a net increase in entropy.

    When ΔH>0 and ΔS>0, the reaction proceeds spontaneously at high temperatures and proceeds spontaneously in the reverse direction at low temperatures.

    When ΔH>0 and ΔS<0, the reaction proceeds spontaneously in the reverse direction.

    When ΔH0, the reaction proceeds spontaneously at all temperatures.

    When ΔH<0 and ΔS<0, the reaction proceeds spontaneously at low temperatures and proceeds spontaneously in the reverse direction at high temperatures.
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