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14 June, 09:56

What is the percent dissociation of a 0.015M solution of hydrofluoric acid given the Ka of HF is 6.3x10-4?

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  1. 14 June, 10:13
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    1) Chemical equilibrium:

    HF + H2O ⇄ H3O (+) + F (-)

    0.15 M - x x + x

    2) Ka = [x]^2 / [0.15 - x]

    3) Solution:

    6.3x10^-4 = [x^2] / (0.15 - x)

    => x^2 = (0.15 - x) * 6.3 * 10^ - 4

    x^2 = 0.0000945 - 0.00063x

    x^2 + 0.00063x - 0.0000945 = 0

    Use the quadratic formula to find the solution: x = 0.00941

    4) percent dissociation:

    % = [0.00941 M / 0.15 M] * 100 = 6.27%

    Answer: 6.27%
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