Which is the stronger acid in each of the following pairs? Explain your reasoning.

a. Phenol or p-hydroxybenzaldehyde

b. m-Cyanophenol or p-cyanophenol

c. o-Fluorophenol or p-fluorophenol

Answer:p-hydroxybenzaldehyde is stronger acid to phenol

para-cyanophenol is stronger acid to meta-cyanophenol

o-fluorophenol is stronger acid to p-fluorophenol.

Explanation:

The PKa tool relative to Ph are used to contrast the pairs.

The pKa of phenol is 10. The pKa of p-hydroxybenzaldehyde is 9.24

The pKa for meta-cyanophenol is 8.61 and the pKa for para-cyanophenol is 7.95.

The pKa value of o-fluorophenol is 8.7, while that of the p-fluorophenol is 9.9. It's obvious that the inductive effect is more dominant at ortho-position, which results in a more acidic nature

The pKa is the pH value at which a chemical species will accept or donate a proton. The lower the pKa, the stronger the acid and the greater the ability to donate a proton in aqueous solution.