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31 January, 23:18

An aqueous solution of glucose has molality of 6.81 and a density of 1.2 g/ml what is the molarity of glucose in the solution

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  1. 31 January, 23:44
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    the molarity is 3.68 moles/L

    Explanation:

    the molality of the solution of sucrose is

    m = moles of glucose / Kg of solvent (water) = 6.81,

    since the molecular weight of glucose is 180.156 gr/mole, then per each kilogram of solvent there is

    6.81 moles*180.156 gr/mole + 1000 gr of water = 2226.86 gr of solution

    from the density

    volume of solution = mass of solution/density = 2286.86 gr / 1.2 gr/ml = 1855.71 ml

    therefore there is 1000 gr of water in 1855.71 ml

    then the molarity M is

    M = moles of glucose / L of solution = (moles of glucose / Kg of solvent) * (Kg of solvent/L of solution) = 6.81 moles/Kg * 1Kg/1.85 L = 3.68 moles/L

    M = 3.68 moles/L

    Note:

    - Would be wrong in this case to assume density of water = 1 Kg/L since the solution is heavily concentrated in glucose and therefore the density of water deviates from its pure value.
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