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6 January, 02:37

Sulfurous acid is a polyprotic acid. Write balanced chemical equations for the sequence of reactions that sulfurous acid can undergo when it's dissolved in water.

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  1. 6 January, 02:39
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    The reactions are:

    H₂SO₃ + H₂ O ⇄ HSO₃⁻ + H₃O⁺

    HSO₃⁻ + H₂O ⇄ SO₃⁻² + H₃O⁺

    Explanation:

    This is the sulfurous acid → H₂SO₃.

    It is a weak diprotic acid and it is diprotic because it can release 2 protons to increase H₃O⁺ from water. As every weak acid, the reactions are in equilibrium, that's why it has two Ka. As it can release protons, it is an acid from Bronsted Lowry and an acid from Arrhenius.

    H₂SO₃ + H₂ O ⇄ HSO₃⁻ + H₃O⁺ Ka₁

    HSO₃⁻ → this is called acid sulfite

    HSO₃⁻ + H₂O ⇄ SO₃⁻² + H₃O⁺ Ka₂

    2H₂O ⇄ H₃O⁺ + OH⁻ Kw

    (Don't forget to put water equation, always)
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