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24 December, 07:36

Calculate the ph of the solution made by adding 0.50 mol of hobr and 0.30 mol of kobr to 1.00 l of water. The value of ka for hobr is 2.0*10-9.

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  1. 24 December, 07:46
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    pH = 8.48

    Explanation:

    HOBr dissociates in water as follows:

    HOBr (aq) ↔ H⁺ (aq) + OBr⁻ (aq)

    With a ka expressed by:

    ka = [H⁺]*[OBr⁻] / [HOBr]

    We rearrange and solve for [H⁺]:

    [H⁺] = ka * [HOBr] / [OBr]

    Because the volume is 1 L, the moles added of HOBr and KOBr (OBr⁻) are also the molar concentration:

    [H⁺] = 2.0x10⁻⁹ * 0.50 / 0.30 [H⁺] = 3.33x10⁻⁹ M

    Finally we calculate the pH:

    pH = - log[H⁺] pH = 8.48
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