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9 May, 23:07

glucose 6‑phosphate+H2O⟶glucose+Pi glucose 6‑phosphate+H2O⟶glucose+Pi K′eq1=270 K′eq1=270 ATP+glucose⟶ADP+glucose 6‑phosphate ATP+glucose⟶ADP+glucose 6‑phosphate K′eq2=890 K′eq2=890 Using this information for equilibrium constants determined at 25∘C, 25∘C, calculate the standard free energy of hydrolysis of ATP. standard free energy:

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  1. 9 May, 23:36
    0
    -30.7 kj/mol

    Explanation:

    The standard free energy for the given reaction that is the hydrolysis of ATP is calculated using the formula: ∆Go ' = - RTln K'eq

    where,

    R = - 8.315 J / mo

    T = 298 K

    For reaction,

    1. K′eq1=270,

    ∆Go ' = - RTln K'eq

    = - 8.315 x 298 x ln 270

    = - 8.315 x 298 x 5.59

    = - 13,851.293 J / mo

    = - 13.85 kj/mol

    2. K′eq2=890

    ∆Go ' = - RTln K'eq

    = - 8.315 x 298 x ln 890

    = - 8.315 x 298 x 6.79

    = - 16.82 kj/mol

    therefore, total standard free energy

    = - 13.85 + (-16.82)

    = - 30.7 kj/mol

    Thus, - 30.7 kj/mol is the correct answer.
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