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24 January, 04:38

When 2.56 g of a compound containing only carbon, hydrogen, and oxygen is burned completely, 4.89 g of CO2 and 3.00 g of h2o are produced. What is the empirical formula of the compound

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  1. 24 January, 04:53
    0
    The empirical formula is CH3O2

    Explanation:

    From The question, number of moles of CO2 = 4.89/44=0.111mol

    Number of moles of H2O=3/18 = 0.1667moles

    Since 1mole of CO2 contains 1mole of carbon and 2 moles of O2,

    Implies that there 0.111 moles of C and 0.222moles of O2

    Similarly also 0.1667moles of water contains 2 moles of H2 hence = 0.333 moles of H2

    Dividing by smallest number = 0.111mol

    For C = 0.111/0.111 = 1

    For H = 0.333 / 0.111 = 3

    For O = 0.222/0.111 = 2

    Hence the empirical formula = CH3O2
  2. 24 January, 05:02
    0
    C2H5O

    Explanation:

    Mass of C = molar mass of C/molar mass of CO2 x mass of CO2

    = 12/44 x 4.89 = 1.3336 g

    Mass of H = molar mass of H2/molar mass of H2O x mass of H2O

    = 2/18 x 3 = 0.33333 g

    Mass of O = mass of compound - mass of C - mass of H

    = 2.56 - 1.3336 - 0.33333 = 0.98307g

    Since moles = mass/atomic mass

    Moles of C : H : O = 1.3336/12 : 0.33333/1 : 0.98307/16

    = 0.1111 : 0.33333 : 0.061

    Dividing by the smallest

    = 2 : 5 : 1

    The empirical formula is C2H5O
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