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21 April, 16:01

In a group 1 analysis, a student obtained a precipitate containing both AgCl and PbCh. Which of the following reagents would enable separation of AgCl (s) from PbCl (s) ? O Hys 0 Na2CO3 o KOH O NH3 O

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  1. 21 April, 16:26
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    We can separate AgCl and PbCl₂ by adding hot water.

    Explanation:

    In order to separate group one salts/ions is important to consider their solubility.

    PbCl₂ is more soluble in water then AgCl and, when we increase water's temperature, PbCl₂ solubility icireases significantly. However, AgCl solubility does not change considerably.

    Therefore, when we add hot water to the solution, the PbCl₂ will be dissolved and AgCl will remain as a precipitate.
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