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29 August, 04:43

Hydrogen cyanide, hcn, is a weak acid. which equation best represents its aqueous chemistry?

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  1. 29 August, 04:52
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    The equations are as follow,

    A) HCN (aq) + H₂O (l) ↔ H₂CN⁺ (aq) + OH⁻ (aq)

    B) H₂O (l) ↔ H⁺ (aq) + OH⁻ (aq)

    C) HCN (aq) ↔ H⁺ (aq) + CN⁻ (aq)

    D) HCN (aq) + H₂O (l) ↔ CN⁻ (aq) + H₃O⁺ (aq)

    E) HCN (aq) ↔ H⁻ (aq) + CN⁺ (aq)

    Answer:

    Option-D is the correct answer.

    Explanation:

    When hydrogen cyanide is added in water it partially ionizes as follow,

    HCN (aq) + H₂O (l) ↔ CN⁻ (aq) + H₃O⁺ (aq)

    Being weak acid it fails to completely dissociate into H⁺ and CN⁻ ions. In this reaction water is acting as a Bronsted Lowery Base and picks proton from from HCN and converts into conjugate acid (i. e. H₃O⁺), while, HCN converts into conjugate Base (i. e. CN⁻).
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