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4 March, 00:58

The statement "Although sulfuric acid is a strong electrolyte, an aqueous solution of H2SO4 contains more HSO4 - ions than SO42 - ions" is The statement "Although sulfuric acid is a strong electrolyte, an aqueous solution of H 2 S O 4 contains more H S O 4 - ions than S O 4 2 - ions" is blank. This is best explained by the fact that H 2 S O 4 blank ... This is best explained by the fact that H2SO4 The statement "Although sulfuric acid is a strong electrolyte, an aqueous solution of H 2 S O 4 contains more H S O 4 - ions than S O 4 2 - ions" is blank. This is best explained by the fact that H 2 S O 4 blank ...

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  1. 4 March, 01:00
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    The statement "Although sulfuric acid is a strong electrolyte, an aqueous solution of H₂SO₄ contains more HSO₄⁻ ions than SO₄²⁻ ions is True. This is best explained by the fact that H₂SO₄ is a diprotic acid where only the first hydrogen completely ionizes.

    Why?

    H₂SO₄ is a diprotic acid. That means that it has two hydrogen ions to give to the solution. The two dissociation reactions are shown below:

    H₂SO₄ + H₂O → HSO₄⁻ + H₃O⁺

    HSO₄⁻ + H₂O ⇄ SO₄²⁻ + H₃O⁺

    As the arrows show, the first dissociation is complete, meaning that all the sulfuric acid that is present initially is dissociated into HSO₄⁻ and H₃O⁺. However, the second dissociation is incomplete, and it's actually an equilibrium with an acid constant (Ka) of 1.2*10⁻².

    That means that if the initial concentration of H₂SO₄ was 1M, the concentration of HSO₄⁻ is going to be 1M as well, but the concentration of SO₄²⁻ is going to be much less than 1M, according to the dissociation constant.

    Have a nice day!
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