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9 November, 17:53

Using the example reaction aA + bB → cC + dD write the potential first order and second order rate laws

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  1. 9 November, 18:18
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    Given the equation aA + bB → cC + dD, which is an irreversible reaction, the most common rate laws are the product of the concentration of the reactants, each raised to a power.

    This is the the general form of such laws.

    r = K [A]^m * [B]^n

    The order of the reaction is the sum of the exponents: m + n.

    For first order reaction m + n = 1, yields to the next potential laws:

    m = 1, n = 0 = > r = k [A]

    m = 0, n = 1 = > r = k [B]

    m=0.5, n = 0.5 = > r = [A]^0.5 [B]^0.5

    And other combinations where the sum of the exponents are 1.

    For second order reactions, m + n = 2, these are some potential laws:

    m = 1, n = 1 = > r = k[A][B]

    m=0, n = 2 = > r = k[B]^2

    m=2, n = 0 = > r = k[A]^2

    m=1.5, n = 0.5 = > r = k[A]^1.5 [B]^0.5

    As you see there are many potential laws all of them with the form

    r = [A]^m [B]^n, being the order of the reaction m + n
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