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21 June, 12:14

you are given mixtures containin gthe following compounds. Which compound in each pair could be separated by stirring the solid mixture with water? (A) NaOH and Ca (OH) 2 (B) MgCl2 and MgF2 (C) Agl and KI (D) NH4Cl and PbCl2

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  1. 21 June, 12:26
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    (A) NaOH and Ca (OH) 2: Ca (OH) 2

    (B) MgCl2 and MgF2: MgF2

    (C) Agl and KI: AgI

    (D) NH4Cl and PbCl2: PbCl2

    Explanation:

    We need to see the solubility in water, at similar temperatures, for each compound and see which one is less soluble than the other:

    NaOH: 1000 g/L (25 °C)

    Ca (OH) 2: 1.73 g/L (20 °C)

    MgCl2: 54.3 g/100 mL (20 °C)

    MgF2: 0.013 g/100 mL (20 °C)

    Agl: 3*10-7g/100mL (20 °C)

    KI: 140 g/100mL (20 °C)

    NH4Cl: 383.0 g/L (25 °C)

    PbCl2: 10.8 g/L (20 °C)

    After the comparison made we can conclude that the less soluble, after saturation of water, will precipitate first.
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