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15 September, 01:02

SeH2 molecule - - How many lone-pairs of electrons are on the central Se atom? H3O + ion - - How many lone-pairs of electrons are on the central O atom? SeO2 molecule - - How many lone-pairs of electrons are on the central Se atom?

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  1. 15 September, 01:16
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    Se as in SeH₂: Two lone pairs.

    O as in H₃O⁺: One lone pair.

    Explanation

    Se is a group 16 element. Both Se and O have six valence electrons in each neutral atom. The structure of an SeH₂ molecule resembles that of a water H₂O molecule. Two Se-H bonds connect the three atoms in each SeH₂ molecule.

    Two valence electrons on the central Se atom would go to the two Se-H bonds. The four valence electrons remaining would form two lone pairs.

    H₃O⁺ has a trigonal pyramidal geometry.

    Each oxygen atom demands 2 electrons to form an octet. Each hydrogen atom demands 1 electrons to form an octet. There are three hydrogen atoms in each H₃O⁺ ion. The charge of + 1 indicates that the ion lacks one electron. It would take an extra electron to fill that gap.

    It takes 2 + 3 * 1 + 1 = 6 extra electrons to ensure an octet for all four atoms in a H₃O⁺ ion. The ion would achieve that configuration by forming 6 / 2 = 3 O-H bonds. The central oxygen atom has six valence electrons when it is neutral. Now it has five in this cation after having lost one to acquire the charge of + 1. Three of the valence electrons go to three O-H bonds. The remaining two become a lone pair.
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