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3 September, 12:38

Calculate the ph of a 0.20 m solution of iodic acid (hio3, ka = 0.17).

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  1. 3 September, 12:43
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    Iodic acid partially dissociates into H + and IO3-

    Assuming that x is the concentration of H + at equilibrium, and sine the equation says the same amount of IO3 - will be released as that of H+, its concentration is also X. The formation of H + and IO3 - results from the loss of HIO3 so its concentration at equilibrium is 0.20 M - x

    Ka = [H+] [IO3-] / [HIO3];

    Initially, [H+] ≈ [IO3-] = 0 and [HIO3] = 0.20;

    At equilibrium [H+] ≈ [IO3-] = x and [HIO3] = 0.20 - x;

    so 0.17 = x² / (0.20 - x);

    Solving for x using the quadratic formula:

    x = [H+] = 0.063 M or pH = - log [H+] = 1.2.
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