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2 March, 22:06

In the important industrial process for producing ammonia (the Haber Process), the overall reaction is: N2 (g) + 3H2 (g) → 2NH3 (g) + 100.4 kJ A yield of NH3 of approximately 98% can be obtained at 200°C and 1,000 atmospheres of pressure. What is the ΔH in kJ of heat released per mole of NH3 (g) formed?

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  1. 2 March, 22:24
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    We are given the Haber Process overall reaction:

    N2 (g) + 3H2 (g) = = = > 2NH3 (g) H = 100.4 kJ

    Yield = 98%

    T = 200 C

    P = 1000 atm

    We need to determine the heat released per mole of NH3 formed.

    solve for the number of moles produced in the process using the ideal gas equation:

    PV = nRT

    1000 atm * 22.4 = n * 0.0821 L atm / mol K * (200+273) K

    n = 576.82 moles * 0.98 = 565.29 moles

    Therefore, the heat released per mole of NH3 is 100.4 kJ/565.29 mole NH3

    ΔH = 0.1776 kJ/mole
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