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2 December, 01:16

A certain liquid has a vapor pressure of 92.0 Torr at 23.0 °C and 351.0 Torr at 45.0 °C. Calculate the value of ΔH°vap for this liquid.

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  1. 2 December, 01:21
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    There is a specific formula to use for these type of problems.

    ln (P2 / P1) = Δvap / R x (1/T1 - 1/T2)

    R = 8.314

    P1 = 92.0 torr

    T1 = 23 C + 273 = 296 K

    P2 = 351.0 torr

    T2 = 45.0 C + 273 = 318 K

    plug the values and solve for the unknown

    ln (351.0 / 92.0) = Δvap / 8.314 x (1/296 - 1/318)

    Δvap = 47630.6 joules
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