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6 November, 15:26

What are the major organic products are formed when the following compounds react with methylmagnesium bromide (CH3MgBr), followed by the addition of dilute acid?

a) propanal

b) propanone

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  1. 6 November, 15:45
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    Major organic products are - (a) propan-1-ol and (b) 2-methylpropan-2-ol

    Explanation:

    methyl magnesium bromide gives nucleophilic addition reaction with carbonyl group. Because methyl magnesium bromide is a strong nucleophile and carbonyl group is a strong electrophilic center.

    Propanal contains an aldehyde group and propanone contains a ketone group. hence they both give nucleophilic addition with methyl magnesium bromide.

    Dilute acid is added to protonate the alkoxide produced during nucleophilic addition.

    Reactions are shown below.
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