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28 November, 11:45

A 425.00-gram sample of a compound decomposes into 196.01 grams of carbon, 41.14 grams of hydrogen, 130.56 grams of oxygen, and 57.29 grams of silicon. Experiments have shown the compound has a molecular weight of 208.329. What is the molecular formula?

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  1. 28 November, 12:14
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    C₈H₂₀O₄Si

    Explanation:

    The moles of each atom (Using atomic weight) are:

    C: 196.01g * (1mol / 12.01g) = 16.32 moles of C

    H: 41.14g * (1mol / 1.01g) = 40.73 moles of H

    O: 130.56g * (1mol / 16g) = 8.16 moles of O

    Si: 57.29g * (1mol / 28.09g) = 2.04 moles of Si

    Dividing in the number of moles of Si to obtain the simplest ratio:

    C: 16.32mol C / 2.04mol: 8

    H: 40.73mol H / 2.04mol: 20

    O: 8.16 mol O / 2.04mol: 4

    Si: 2.04mol / 2.04mol: 1

    Thus, empirical formula of the compound is:

    C₈H₂₀O₄Si.

    Molar mass for this formula is:

    12.01g/mol * 8 + 1.01g/mol * 20 + 16g/mol * 4 + 28.09g/mol * 1 =

    208.37 g/mol ≈ Molecular weight obtained in the experiment.

    Thus, molecular formula of the compound is:

    C₈H₂₀O₄Si
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