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16 April, 03:16

The relative rates of reaction of ethane, toluene, and ethylbenzene with bromine atoms have been measured.

The most reactive hydrocarbon undergoes hydrogen atom abstraction a million times faster than does the least reactive one.

Arrange these hydrocarbons in order of decreasing reactivity.

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  1. 16 April, 03:25
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    Reactivity: Ethyl benzene > Toluene > Ethane

    Explanation:

    The order of reactivity depends on how easily the most reactive hydrogen can be abstracted.

    The order of reactivity of hydrogen is : 1° < 2° < 3° < Benzyllic based on the stabilizing effects like inductive effect, hyperconjugation, resonance effect.

    In ethane, all the hydrogen present are 1°. In toluene, the most reactive hydrogen is benzyllic. In Ethyl Benzene, the most reactive hydrogen is 2° as well as benzyllic.

    Hence the order of decreasing reactivity : Ethyl Benzene, Toluene, Ethane.
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