14 December, 02:43
Calculate the partial pressure of phosgene that is in equilibrium with a mixture of 0. 025 atm of carbon monoxide and 0. 003 5 atm of chlorine at 600°c.
14 December, 03:01
According to the reaction equation:
by using ICE table:
CO (g) + Cl2 (g) ↔ COCl2 (g)
initial 0.025 0.0035 0
change - X - X + X
Equ (0.025-X) (0.0035-X) X
Kp = P (COCl2) / P (CO}*P (Cl2) when Kp = 0.2
0.2 = X / (0.025-X) (0.0035-X) by solving this equation for X
∴ X = 1.74x10^-5
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» Calculate the partial pressure of phosgene that is in equilibrium with a mixture of 0. 025 atm of carbon monoxide and 0. 003 5 atm of chlorine at 600°c.