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18 September, 21:46

Using molecular orbital theory, explain why the removal of one electron in O2 strengthens bonding, while the removal of one electron in N2 weakens bonding?

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  1. 18 September, 21:53
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    First you have a knowledge of bond order which is

    B. O = (no. of electrons in bonding orbital - no. of electrons in non-bonding orbital) : 2

    Note:

    bond strength is directly proportional to bond order.

    For oxygen:

    B. O = (6-2) / 2 = 2; after the removal of two electrons (removal occur from non-bonding orbital)

    B. O = (6-0) / 2 = 3 (As B. O increased bond strength increased)

    For Nitrogen:

    B. O = (6-0) / 2 = 3; after the removal of two electrons (removal occur from bonding orbital)

    B. O = (4-0) / 2 = 2 (As B. O decreased bond strength decreased)
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