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20 June, 21:22

The following reaction plays a key role in the destruction of ozone In the atmosphere:

Cl (g) + O3 (g) - -> ClO (g) + O2 (g)

Given that S degree for CIO is 218.9J / (mol. K), use standard molar entropies (S degree) to calculate the delta S for this reaction.

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  1. 20 June, 21:39
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    19.91 J/K

    Explanation:

    The entropy is a measure of the randomness of the system, and it intends to increase in nature, thus for a spontaneous reaction ΔS > 0.

    The entropy variation can be found by:

    ΔS = ∑n*S° products - ∑n*S° reactants

    Where n is the coefficient of the substance. The value of S° (standard molar entropy) can be found at a thermodynamic table.

    S°, Cl (g) = 165.20 J/mol. K

    S°, O3 (g) = 238.93 J/mol. K

    S°, O2 (g) = 205.138 J/mol. K

    So:

    ΔS = (1*205.138 + 1*218.9) - (1*165.20 + 1*238.93)

    ΔS = 19.91 J/K
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