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25 March, 13:28

In an experiment, hydrogen is collected in a 455-milliliter jar above water at a pressure of 101,3 kilopascals and a

temperature of 29.1°C. In addition to hydrogen, there is some water vapor in the jar. If the partial pressure of the water vapor is 4.0 kilopascals, how many moles of hydrogen are generated during the experiment?

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  1. 25 March, 13:44
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    n = 1.9 * 10⁻⁵ mol

    Explanation:

    Given dа ta:

    Volume of hydrogen gas = 455 mm

    Pressure of hydrogen gas = 101.3 kpa

    Temperature = 29.1°C

    Partial pressure of water vapor = 4.0 kpa

    Number of moles of hydrogen gas = ?

    Solution:

    First of all we will convert the units.

    Pressure of hydrogen gas = 101.3 kpa = 101.3/101 = 1 atm

    Partial pressure of water vapor = 4.0 kpa = 4.0 / 101 = 0.04 atm

    Temperature = 29.1 + 273 = 302.1 K

    Volume of hydrogen gas = 455 / 1*10⁶ = 0.000455 L

    Now we will calculate the total pressure.

    Total pressure = Partial pressure of hydrogen gas + partial pressure of water vapors

    Total pressure = 1 atm + 0.04 atm

    Total pressure = 1.04 atm

    Now we will calculate the number of moles;

    PV = nRT

    n = PV/RT

    n = 1.04 atm * 0.000455 L / 0.0821 atm. L / mol. K * 302.1 K

    n = 0.00047 / 24.80/mol

    n = 1.9 * 10⁻⁵ mol
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