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4 January, 17:01

Measurements show that the enthalpy of a mixture of gaseous reactants increases by 215. kJ during a certain chemical reaction, which is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that - 155. kJ of work is done on the mixture during the reaction.

Calculate the change in energy of the gas mixture during the reaction. Round your answer to 2 significant digits.

Is the reaction exothermic or endothermic?

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  1. 4 January, 17:08
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    a) ΔU = 370 KJ

    b) Endothermic

    Explanation:

    a)

    The change in energy of the mixture can be given by first law of thermodynamics as:

    ΔQ = ΔU + W

    ΔU = ΔQ - W

    where,

    ΔQ = change in heat energy of system

    ΔU = Change in internal energy of gases

    W = Work done on gases = - 155 KJ

    For an isobaric process (i. e constant pressure) we know that:

    ΔQ = change in enthalpy = ΔH

    ΔQ = 215 KJ

    Therefore, using values in the equation, we get:

    ΔU = 215 KJ - (-155 KJ)

    ΔU = 370 KJ

    b)

    Since, the enthalpy of products is greater than the reactants. Therefore, this is an endothermic reaction.
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