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14 September, 10:35

At 2000 ∘c the equilibrium constant for the reaction 2no (g) ⇌n2 (g) + o2 (g) is kc=2.4*103. part a if the initial concentration of no is 0.171 m, what is the equilibrium concentration of no?

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  1. 14 September, 10:50
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    [NO] = 1.72 x 10⁻³ M.

    Explanation:

    For the reaction:

    2NO (g) ⇌ N₂ (g) + O₂ (g),

    Kc = [N₂][O₂] / [NO]².

    At initial time: [NO] = 0.171 M, [N₂] = [O₂] = 0.0 M. At equilibrium: [NO] = 0.171 M - 2x, [N₂] = [O₂] = x M.

    ∵ Kc = [N₂][O₂] / [NO]².

    ∴ 2400 = x² / (0.171 - 2x) ².

    Taking the aquare root for both sides:

    √ (2400) = x / (0.171 - 2x)

    48.99 = x / (0.171 - 2x)

    48.99 (0.171 - 2x) = x

    8.377 - 97.98 x = x

    8.377 = 98.98 x.

    ∴ x = 8.464 x 10⁻².

    ∴ [NO] = 0.171 - 2 (8.464 x 10⁻²) = 1.72 x 10⁻³ M.

    ∴ [N₂] = [O₂] = x = 8.464 x 10⁻² M.
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