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24 December, 07:12

Consider the SCl2 molecule. (a) What is the electron config - uration of an isolated S atom? (b) What is the electron con - figuration of an isolated Cl atom? (c) What hybrid orbitals should be constructed on the S atom to make the S-Cl bonds in SCl2? (d) What valence orbitals, if any, remain unhybrid - ized on the S atom in SCl2?

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  1. 24 December, 07:35
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    (a) 1s² 2s² 2p⁶ 3s² 3p⁴

    (b) 1s² 2s² 2p⁶ 3s² 3p⁵

    (c) sp³

    (d) No valence orbital remains unhybridized.

    Explanation:

    Consider the SCl₂ molecule.

    (a) What is the electron configuration of an isolated S atom?

    S has 16 electrons. Its electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁴.

    (b) What is the electron configuration of an isolated Cl atom?

    Cl has 17 electrons. Its electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁵.

    (c) What hybrid orbitals should be constructed on the S atom to make the S-Cl bonds in SCl₂?

    SCl₂ has a tetrahedral electronic geometry. Therefore, the orbital 3s hybridizes with the 3 orbitals 3 p to form 4 hybrid orbital sp³.

    (d) What valence orbitals, if any, remain unhybridized on the S atom in SCl₂?

    No valence orbital remains unhybridized.
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