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12 April, 05:47

In the compound k[co (c2o4) 2 (h2o) 2] (where c2o42 - = oxalate) the oxidation number and coordination number of cobalt are, respectively

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  1. 12 April, 05:50
    0
    Let's Assign Symbols to molecules like,

    C₂O₄ = X

    and

    H₂O = Y

    Then,

    K [ Co (X) ₂ (Y) ₂ ]

    As, Potassium (K) has a O. N = + 1

    To neutralize, the coordination sphere must have - 1 oxidation number.

    So,

    [ Co (X) ₂ (Y) ₂ ] = - 1

    As,

    O. N of X = - 2

    Then

    O. N of (X) ₂ = - 4

    Also,

    O. N of H₂O is zero as it is neutral, So,

    [Co - 4 + 0 ] = - 1

    Or,

    Co = - 1 + 4

    Co = + 3

    Result:

    Oxidation Number of Coordination Sphere is - 1 and Oxidation Number of Cu is + 3.
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