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27 August, 12:20

An NaCl solution is prepared by dissolving 20.0 g NaCl in 150.0 g of water at 25°C. What is the vapor pressure of the solution if the vapor pressure of water at 25°C is 23.56 torr? Group of answer choices

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  1. 27 August, 12:45
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    Vapor pressure for the solution is 21.70 Torr

    Explanation:

    Vapor pressure lowering → Colligative property

    P° = Vapor pressure of pure solvent

    P' = Vapor pressure of solution

    Xm = Mole fraction of solute → Moles of solute / Total moles

    Total moles = Moles of solute + moles of solvent

    Formula = P° - P' = P°. Xm. i

    Let's determine the moles of solute and solvent

    20 g / 58.45 g/mol = 0.342 moles NaCl

    150 g / 18 g/mol = 8.333 moles H₂O

    Total moles → 8.333 + 0.342 = 8.675 moles

    Mole fraction of solute = 0.342 / 8.675 = 0.039

    i → NaCl ⇒ Na⁺ + Cl⁻ i = 2 (Van't Hoff factor, number of ions dissolved)

    Let's replace the data, that was obtained from the problem.

    23.56 Torr - P' = 23.56 Torr. 0.039. 2

    P' = - (23.56 Torr. 0.039. 2 - 23.56 Torr) → 21.70 Torr
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