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9 May, 08:27

Consider the reaction between nis2 and o2: 2nis2 (s) + 5o2 (g) →2nio (s) + 4so2 (g) when 11.2 g of nis2 are allowed to react with 5.43 g of o2, 4.89 g of nio are obtained.

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  1. 9 May, 08:53
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    M (NiS₂) = 11.2 g.

    n (NiS₂) = m (NiS₂) : M (NiS₂).

    n (NiS₂) = 11.2 g : 122.8 g/mol.

    n (NiS₂) = 0.091 mol.

    m (O₂) = 5.43 g.

    n (O₂) = 5.43 g : 32 g/mol.

    n (O₂) = 0.17 mol; limiting reactant.

    From chemical reaction: n (NiS₂) : n (O₂) = 2 : 5.

    0.091 mol : n (O₂) = 2 : 5.

    n (O₂) = 0.2275 mol, not enough.

    n (NiO) = 4.89 g.

    n (O₂) : n (NiS) = 5 : 2.

    n (NiS) = 0.068 mol.

    m (NiS) = 0.068 mol · 74.7 g/mol = 5.08 g.

    percent yield = 4.89 g / 5.08 g · 100% = 96.2%.
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