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14 January, 17:35

The reaction of H2 with F2 produces HF with ΔH = - 269 kJ/mol of HF. If the H-H and H-F bond energies are 432 and 565 kJ/mol, respectively, what is the F-F bond energy?

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  1. 14 January, 18:03
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    The bond energy of F-F = 429 kJ/mol

    Explanation:

    Given:

    The bond energy of H-H = 432 kJ/mol

    The bond energy of H-F = 565 kJ/mol

    The bond energy of F-F = ?

    Given that the standard enthalpy of the reaction:

    H₂ (g) + F₂ (g) ⇒ 2HF (g)

    ΔH = - 269 kJ/mol

    So,

    ΔH = Bond energy of reactants - Bond energy of products.

    -269 kJ/mol = [1. (H-H) + 1. (F-F) ] - [2. (H-F) ]

    Applying the values as:

    -269 kJ/mol = [1. (432 kJ/mol) + 1. (F-F) ] - [2. (565 kJ/mol) ]

    Solving for, The bond energy of F-F, we get:

    The bond energy of F-F = 429 kJ/mol
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