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8 March, 20:23

Calculate kp at 298.15 k for the reactions (a), (b), and (c) using δg°f values.

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  1. 8 March, 20:51
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    (a) 2NO (g) + O₂ (g) ⇄2NO₂ (g) kp

    (b) 2N₂O (g) ⇄2NO (g) + N₂ (g) kp

    (c) N₂ (g) + O₂ (g) ⇄ 2NO (g) kp

    Now A is

    2NO + O₂⇄2NO₂

    ΔG° = ΔG° products - ΔG reactants

    =2 * 51.3 - (256.6)

    -70.6kJ/mol.

    ΔG° = - RT Inkp

    -70.6 = - 8.314 * 10⁻³ ˣ 298.15 ˣInkJ

    InkJ = 28.48

    kp=2.34 ˣ 10¹²

    B is

    ΔG° = 2 * 86.6 - 2 * 104.2 = - 35.2

    -35.2 = 8.314 * 10⁻³ ˣ 298.15 ˣInkJ

    InkJ = 14.2

    kp = 1.47ˣ 10⁶

    C is

    It is also similar

    kp = 4.62 ˣ 10⁻³I
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