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21 August, 14:52

The decomposition of N2O5 in carbon tetrachloride proceeds as follows: 2N2O5→4NO2+O2 The rate law is first order in N2O5. At 64 ∘C the rate constant is 4.82*10-3s-1. You may want to reference (Pages 576 - 581) Section 14.3 while completing this problem. Part A Which of the following is the rate law for this reaction? Which of the following is the rate law for this reaction? rate=4.82*10-3s-1[N2O5]2 rate=2.41*10-3s-1[N2O5] rate=4.82*10-3s-1[N2O5] rate=9.64*10-3s-1[N2O5]

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  1. 21 August, 15:12
    0
    r = 2.41 E-3 s-1 [ N2O5 ]

    Explanation:

    2N2O5 → 4NO2 + O2

    ∴ k = 4.82 E-3 s-1

    ⇒ r = k [ N2O5 ]/2

    ⇒ r = (4.82 E-3 s-1 [ N2O5 ]) / 2

    ⇒ r = 2.41 E-3 s-1 [ N2O5 ]
  2. 21 August, 15:19
    0
    rate = 4.82x10⁻³*[N₂O₅]

    Explanation:

    The rate of a reaction represents how much moles of the reactant is disappearing along the time, and for a reaction with only one reactant, it can be calculated by:

    rate = k*[reactant]ⁿ

    Where k is the rate constant, [reactant] is the initial concentration of the reactant, and n is the order of the reaction, which is determined by experiments. So, if the rate law is first order, n = 1:

    rate = 4.82x10⁻³*[N₂O₅]
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