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19 November, 08:32

Calculate the ph of 1.00 l of a buffer that is 1.00 m in acetic acid and 1.00 m in sodium acetate after the addition of 0.550 mole of naoh.

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  1. 19 November, 08:56
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    Initial moles of sodium acetate = acetic acid = 1 m * 1 L = 1 moles

    [ acetate ] after adding NaOH = 1 mol + 0.55 mol = 1.55 M

    [acetic acid] after adding NaOH = 1 mol - 0.55 mol = 0.45 M

    According to Handerson-Hasselblach equation:

    PH = Pka + ㏒ [ acetate]/[acetic acid]

    when Pka = 4.74

    so, by substitution:

    ∴PH = 4.74 + ㏒[1.55/0.45]

    ∴ PH = 5.28
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