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16 September, 08:10

A 1.50-g sample of hydrated copper (ii) sulfatewas heated carefully until it had changed completely to anhydrous copper (ii) sulfate () with a mass of 0.957 g. determine the value of x. [this number is called the number of waters of hydration of copper (ii) sulfate. it specifies the number of water molecules per formula unit of in the hydrated crystal.]

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  1. 16 September, 08:29
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    CuSO₄·xH₂O → CuSO₄ + xH₂O

    M (CuSO₄) = 159.61 g/mol

    M (H₂O) = 18.02 g/mol

    m (CuSO₄·xH₂O) = 1.50 g

    m (CuSO₄) = 0.957 g

    m (CuSO₄·xH₂O) / M (CuSO₄·xH₂O) = m (CuSO₄) / M (CuSO₄)

    M (CuSO₄·xH₂O) = M (CuSO₄) + xM (H₂O)

    m (CuSO₄·xH₂O) / {M (CuSO₄) + xM (H₂O) }=m (CuSO₄) / M (CuSO₄)

    M (CuSO₄) + xM (H₂O) = m (CuSO₄·xH₂O) M (CuSO₄) / m (CuSO₄)

    xM (H₂O) = m (CuSO₄·xH₂O) M (CuSO₄) / m (CuSO₄) - M (CuSO₄)

    x=M (CuSO₄) / M (H₂O) {m (CuSO₄·xH₂O) / m (CuSO₄) - 1}

    x=159.61/18.02*{1.50/0.957-1}=5.0

    x=5

    CuSO₄·5H₂O
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