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19 November, 02:27

For a certain reaction, the frequency factor A is 5.0 * 109 s-1 and the activation energy is 16.3 kJ/mol. What is the rate constant for the reaction at 79°C

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  1. 19 November, 02:54
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    K (79°C) = 1.906 E7 s-1

    Explanation:

    Arrhenius eq:

    K (T) = A e∧ ( - Ea/RT)

    ∴ A = 5.0 E9 s-1

    ∴ Ea = 16.3 KJ/mol

    ∴ R = 8.314 E-3 KJ/K. mol

    ∴ T = 79°C ≅ 352 K ⇒ K = ?

    ⇒ K (79°C) = (5.0 E9 s-1) e∧[ - (16.3KJ/mol) / (8.314 E-3 KJ/K. mol) (352 K) ]

    ⇒ K (79°C) = (5.0 E9 s-1) e∧ ( - 5.5697)

    ⇒ K (79°C) = (5.0 E9 s-1) * (3.811 E-3)

    ⇒ K (79°C) = 1.906 E7 s-1
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