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27 April, 02:34

Calculate the de Broglie wavelength for (a) an electron with a kinetic energy of 100eV, (b) a proton with a kinetic energy of 100 eV, and (c) an electron in the first Bohr orbit of a hydrogen atom.

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  1. 27 April, 02:40
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    Broglie wavelength: electron 1.22 10⁻¹⁰ m, proton 2.87 10⁻¹² m, hydrogen atom 7.74 10⁻¹² m

    Explanation:

    The equation given by Broglie relates the momentum of a particle with its wavelength.

    p = h / λ

    In addition, kinetic energy is related to the amount of movement

    E = ½ m v²

    p = mv

    E = ½ p² / m

    p = √2mE

    If we clear the first equation and replace we have left

    λ = h / p =

    λ = h / √2mE

    Let's reduce the values that give us SI units

    1 ev = 1,602 10⁻¹⁹ J

    E1 = 100 eV (1.6 10⁻¹⁹ J / 1eV) = 1.6 10⁻¹⁷ J

    We look in tables for the mass of the particle and the Planck constant

    h = 6,626 10-34 Js

    me = 9.1 10-31 Kg

    mp = 1.67 10-27 Kg

    Now let's replace and calculate the wavelengths

    a) Electron

    λ1 = 6.6 10⁻³⁴ / √ (2 9.1 10⁻³¹ 1.6 10⁻¹⁷) = 6.6 10⁻³⁴ / 5.39 10⁻²⁴

    λ1 = 1.22 10⁻¹⁰ m

    b) Proton

    λ2 = 6.6 10-34 / √ (2 1.67 10⁻²⁷ 1.6 10⁻¹⁷) = 6.6 10⁻³⁴ / 2.3 10⁻²²

    λ2 = 2.87 10⁻¹² m

    c) Bohr's first orbit

    En = 13.606 / n2 [eV]

    n = 1

    E1 = 13.606 eV

    E1 = 13,606 ev (1.6 10⁻¹⁹ / 1eV) = 21.77 10⁻¹⁹ J

    λ3 = 6.6 10⁻³⁴ / √ (2 1.67 10⁻²⁷ 21.77 10⁻¹⁹) = 6.6 10⁻³⁴ / 8.52 10⁻²³

    λ3 = 0.774 10⁻¹¹ m = 7.74 10⁻¹² m
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